Mexico City's government ordered traffic restrictions on Tuesday and recommended people stay indoors due to serious air pollution, issuing its second-highest alert warning for ozone levels for the first time in 13 years.

While conditions persisted, residents were better off inside between 1 p.m. and 7 p.m., should refrain from vigorous exercise in the open and curb sporting activities to avoid respiratory problems, the city said in a statement on Monday.

The government said the alert stemmed from an "extraordinary increase" in ozone concentration due to the presence of a high pressure system and intense solar radiation around greater Mexico City, which is home to more than 20 million people.

Not since September 2002 had the city issued a "phase one" pollution warning for elevated levels of ozone.

A phase one alert was last issued for particle pollution on New Year's Day 2005, a time when air quality was likely affected by heavy use of firecrackers, a city official said.

Ozone, which is a key ingredient of smog, is a form of oxygen created by the reaction of sunlight with air containing other pollutants such as hydrocarbons and nitrogen oxide.

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It can cause breathing difficulties and worsen heart disease. Children and the elderly are especially at risk.

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